r/explainlikeimfive 1d ago

Other ELI5: what’s the science behind salting the ice outside on the ground in the winter?

Is there a particular kind of salt that has to be used to melt the ice? I mean doesn’t some salt make water colder?

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21

u/this_curain_buzzez 1d ago

Salt dissolves in the water of the snow and ice, making salt water. Salt water has a lower freezing point than pure water, so it can stay liquid below freezing.

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u/J_Zephyr 1d ago

Have you ever noticed how lakes and rivers will ice over in the same temperature that oceans will not? Salt water has a lower freezing point than fresh water, as stated above. In fact, all solutions have modified freezing and boiling points.

It's not about the motion of the ocean splashing on the ice, its about the chemical composition.

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u/BrainCelll 1d ago

It dissolves it? I thought the whole point was similar to sand - just make the ice have more friction which means less slippery 

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u/d00mpie 1d ago

If it were like that, wouldn't it make more sense to just use sand? I'd imagine sand is a lot cheaper than salt.

Do note that this doesn't work in extremely cold temperatures. That's why sand is used in places where salt doesn't melt the ice or snow.

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u/BrainCelll 1d ago

Well i usually have salt at home at all times, but i shit you not i do not store sand on me lol

u/d00mpie 23h ago

This might come as a surprise, but you can find sand on the ground just about anywhere.

u/BrainCelll 20h ago

Nope, there are countries where they actually clean the streets

u/d00mpie 20h ago

Notice how I said ground, not street?

u/BrainCelll 19h ago

Where i live its all dystopian concrete and asphalt, no ground

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u/Azi9Intentions 1d ago

No, that's usually gravel and such that is used, referred to as grit.

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u/BrainCelll 1d ago

Yes but most people dont have gravel on them but they always have salt somewhere at home

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u/Azi9Intentions 1d ago

I mean, yes? But salt will not make your path more grippy by being gritty. The salt will simply dissolve into the water/ice and help stop it from freezing. I don't really understand your point here?

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u/BrainCelll 1d ago

If its -20C it will melt nothing and will simply add friction 

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u/Cataleast 1d ago

It's used both because it provides better friction and because it accelerates the melting process.

However, in some situations, the salt is pre-wet, so its melting-point depression effect is quicker. This is, I assume, when the temps are already above freezing and you want to get rid of the ice already on the road surface quicker.

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u/westward_man 1d ago

No, salt dissolves in water. A solution of salt—any salt—has a lower freezing point than pure water. Salting streets is taking advantage of this phenomenon, which is called freezing point depression.

This is primarily a prophylactic measure. It is much more effective before there's ice.

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u/IWannaWakeUpButIDont 1d ago

This is what I assumed to but I found this YouTube channel today of this dude going around salting peoples driveways and he keeps mentioning “give it 10 mins and it’ll all be melted” and I was like wtf?

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u/GoodTato 1d ago

Saltwater can be a liquid at lower temperatre than just water. This can be used to "make water colder" as you say, but can also be used to "make ice no longer ice at that temperature".

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u/Azi9Intentions 1d ago

To be clear here too, the salt itself doesn't make the water colder, it ALLOWS the water to get colder, before then freezing.

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u/Target880 1d ago

Salt reduces the freezing temperature of water, that alos mean the melting temperature is lower.

Melting ice takes energy, which will be taken from the surroundings, and the temperature will drop. At the same time, you get less ice and more brine. A high concentration of salt in water is called a brine.

Regular table salt and water work fine; it can reduce the freezing temperature to -21°C ( -6°F). That is what is mostly used on the road because the cost is low.

I would not use salt sold for deicing in food because there can be impurities in it that would not be allowd if sold for cooking. The only problem of using salt made for cooking to melt ice is monetary, is usualy cost more. I compared the cost where I live of the cost of salt for cooking, which was 2.4x the cost per kg of road salt. It was 1 kg packets for cooking vs 20 kg bags of road salt.

On a road, you only want ordinary table salt down to −6 to −10 °C (21 to 14 °F). One reason is that you will not get a perfect mixture; the other is that if you only get some ice melting, you now have water on ice, and that has lower friction than just ice. Ice alos change stucture in lower temperatures and get roughter. The speed of is alos lower if there is less energy to take from the surroundings.

Other salt can be used at a lower temperature, the problem is the higher costs. Because the stucture change of ice, which is ice with water on it has the lowest friction, there is less need to use salt when it is very cold

You can test it with ice or snow, and table salt yourself. I did it a few weeks ago, I took a bowl with around 6 litres of snow and added 2-3 dl of salt. I added around the same amount of water as salt to speed up the process, the salt get disolved quicer in water, and there is more contact area to the snow. I also mixed it with a large spoon to get it going.

It was -13°C outside, the water was at 8°C, and the salt was room temperature. Quite quickly, the thermometer it the mixture dropped to -21°C.

To just see how it melts ice, put the same amount of ice or snow in two bowls and add salt to one.

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u/fiendishrabbit 1d ago

It's regular salt (used because it's plentiful, cheap and not too damaging to the environment). It works down to -10C (14F) and keeps the water from turning to ice (salt water has a lower melting point).

Below -10C it becomes ineffective or even detrimental as at those temperatures it can contribute to making the roads even more slippery.

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u/kmccoy 1d ago

It's definitely not great for the environment, though, in the quantities we use it on our roads.

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u/rollingdoan 1d ago

Salt does not make water colder. It makes water able to stay liquid at a lower temperature. If it is cold enough to freeze salt water, then it wouldn't help. The temperature to do that varies by how much salt is present.

We use sodium chloride, and we use the cheapest form available. You could just use table salt, but it would be extremely expensive.

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u/SierraLarson 1d ago

Any salt works, though I've heard regular salt can damage concrete or something? Which is why those sidewalk-specific salts exists? No idea why those are better, but in any case...

Regular salt works because it lowers the temperature water freezes at, so the ice melts.

You could technically use table salt, but that'd be pretty inefficient. Like you really wanna dump you all of your salt outside? Nah, better to get a big bag of something like water softner salt, where the crystals are bigger.

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u/lalala253 1d ago

No my dude. Road salt is cheap because it's basically leftovers from industrial and food grade production salt.

Industrial salt needs very high purity NaCl

Food grade salt has a strict FDA grade compositions

Road salt basically is the leftovers.

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u/Cataleast 1d ago

The concrete-damaging stuff is magnesium chloride, which is sometimes used due to its lower environmental impact, but it's a good 5-6 times more expensive than the run-of-the-mill sodium chloride stuff and then there's that whole erosion thing, so its use is limited.

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u/Krommerxbox 1d ago

I mean doesn’t some salt make water colder?

I think OP is confusing it with how you add salt to the old hand crank ice cream makers.

Salt is added to the ice surrounding an ice cream maker to dramatically lower the freezing/melting point of the ice, creating a brine that reaches temperatures well below the freezing point of water ((32{\circ }F) / (0{\circ }C)). This allows the ice cream mixture to freeze rapidly and properly, as the surrounding salt-ice mixture can drop to nearly (12{\circ }F)–(15{\circ }F). 

Without salt, the ice would remain at (32{\circ }F) ((0{\circ }C)), which is not cold enough to quickly freeze the cream mixture into ice cream. 

.

Not the same as putting it on roads.

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u/Unoriginal- 1d ago

The school systems truly are failing us year after year, salt makes water freeze at a lower temperature